固定污染源廢氣甲硫醇8種硫有機(jī)物，液化石油氣，二甲醚，甲縮醛，乙縮醛，乙醇，室內(nèi)空氣，焦?fàn)t煤氣，煉廠氣，變壓器油溶解氣，裂解進(jìn)樣器，消毒劑，氨水，氨氣，變壓器油溶解氣，室內(nèi)空氣TVOC，裂解進(jìn)樣器，增塑劑，增塑劑，塑化劑，乙縮醛，乙酸，甲酸，氨水，氨氣

固定污染源廢氣甲硫醇8種硫有機(jī)物
固定污染源廢氣甲硫醇8種硫有機(jī)物 詳細(xì)信息：


名稱：毛細(xì)管柱
固定相：100%二甲基聚硅氧烷固定液
規(guī)格：60m*0.32mm*1.04um
型號(hào)：SE-30
應(yīng)用：HJ 1078-2019 固定污染源廢氣 甲硫醇等8種含硫有機(jī)化合物的測(cè)定 氣袋采樣-預(yù)濃縮/氣相色譜-質(zhì)譜法

為貫徹《中華人民共和國(guó)環(huán)境保護(hù)法》和《中華人民共和國(guó)大氣污染防治法》，保護(hù)生態(tài)環(huán)境，保障人體健康，規(guī)范固定污染源廢氣中含硫有機(jī)化合物的測(cè)定方法，制定本標(biāo)準(zhǔn)。本標(biāo)準(zhǔn)規(guī)定了測(cè)定固定污染源廢氣中甲硫醇等8種含硫有機(jī)化合物的氣袋采樣-預(yù)濃縮/氣相色譜-質(zhì)譜法。本標(biāo)準(zhǔn)的附錄A為規(guī)范性附錄，附錄B和附錄C為資料性附錄。本標(biāo)準(zhǔn)為發(fā)布。

本標(biāo)準(zhǔn)規(guī)定了測(cè)定固定污染源廢氣中甲硫醇等 8 種含硫有機(jī)化合物的氣袋采樣-預(yù)濃縮/ 氣相色譜-質(zhì)譜法。 本標(biāo)準(zhǔn)適用于固定污染源廢氣中甲硫醇、乙硫醇、甲硫醚、甲乙硫醚、二硫化碳、乙硫 醚、二甲二硫、噻吩共 8 種含硫有機(jī)化合物的測(cè)定。 當(dāng)取樣量為 50.0 ml 時(shí)，本標(biāo)準(zhǔn)測(cè)定的含硫有機(jī)化合物的方法檢出限為 0.01～0.02 mg/m3， 測(cè)定下限為 0.04～0.08 mg/m3，詳見附錄 A。

用氣袋采集固定污染源廢氣，經(jīng)冷阱濃縮、熱解析后，進(jìn)入氣相色譜分離，用質(zhì)譜檢測(cè) 器進(jìn)行檢測(cè)。通過(guò)與標(biāo)準(zhǔn)物質(zhì)質(zhì)譜圖和保留時(shí)間比較定性，內(nèi)標(biāo)法定量。


固定污染源廢氣甲硫醇8種硫有機(jī)物 測(cè)試譜圖：



8 kinds of sulfur organic compounds in stationary pollution source exhaust gas methyl mercaptan
8 kinds of sulfur organic compounds in stationary pollution source exhaust gas methyl mercaptan Details:


Name: Capillary Column
Stationary phase: 100% dimethyl polysiloxane stationary solution
Specification: 60m*0.32mm*1.04um
Model: SE-30
Application: HJ 1078-2019 Fixed pollution source waste gas, methyl mercaptan and other 8 sulfur-containing organic compounds, air bag sampling-preconcentration/gas chromatography-mass spectrometry

In order to implement the "Environmental Protection Law of the People's Republic of China" and "The Air Pollution Prevention Law of the People's Republic of China", protect the ecological environment, protect human health, and standardize the determination method of sulfur-containing organic compounds in the exhaust gas of fixed pollution sources, this standard is formulated. This standard specifies the air bag sampling-pre-concentration/gas chromatography-mass spectrometry method for the determination of 8 sulfur-containing organic compounds such as methyl mercaptan in the exhaust gas of stationary sources. Appendix A of this standard is a normative appendix, and Appendix B and Appendix C are informative appendices. This standard is issued for the first time.

This standard specifies the air bag sampling-pre-concentration/gas chromatography-mass spectrometry method for determining 8 sulfur-containing organic compounds such as methyl mercaptan in the exhaust gas of stationary sources. This standard is applicable to the determination of 8 sulfur-containing organic compounds in exhaust gas from stationary pollution sources, including methyl mercaptan, ethyl mercaptan, methyl sulfide, methyl ethyl sulfide, carbon disulfide, ethyl sulfide, dimethyl disulfide, and thiophene. When the sampling volume is 50.0 ml, the detection limit of the method for the determination of sulfur-containing organic compounds in this standard is 0.01～0.02 mg/m3, and the lower limit of determination is 0.04～0.08 mg/m3. See Appendix A for details.

The waste gas from a fixed pollution source is collected with an air bag, concentrated by a cold trap and thermally analyzed, and then separated into a gas chromatograph for detection by a mass detector. It is qualitatively compared with the mass spectrum and retention time of the standard material, and quantified by the internal standard method.


8 kinds of sulfur organic compounds in stationary pollution source exhaust gas methyl mercaptan test spectrum: